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Strengthening in and fracture behaviour of CNT and carbon-fibre-reinforced epoxy–matrix hybrid composite

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Abstract

Advanced materials such as continuous fibre-reinforced polymer matrix composites offer significant enhancements in strength and fracture resistance properties as compared with their bulk, monolithic counterparts. In the present work, mode-I (tensile) fracture behaviour of the neat epoxy (without nano- or hybrid reinforcements), nanocomposite (with amino-functionalized multi-walled carbon nanotube (MWCNT) reinforcement to neat epoxy) and hybrid composite (with amino MWCNT and carbon fibre reinforcements to neat epoxy) along with their flexural strength and interlaminar shear strength has been reported and discussed. Limited topological studies have also been conducted to understand the nature of material fracture and its dependence on the notch orientation. The results thus obtained are analysed and discussed in detail to elucidate: (i) alignment of fibre and its influence on the anisotropy in strength and fracture resistance, (ii) dependence of notch root radii on the apparent fracture toughness and concurrence to strain-controlled fracture and (iii) finally, the nature of JR curves. The results thus obtained have revealed that the resistance to fracture is significantly increased with the addition of amino-functionalized MWCNTs and carbon fibres. In the hybrid composite, fracture resistance is greater in the longitudinal orientation of fibres than in the transverse orientation and it exhibits a significantly higher strength–fracture toughness combination.

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References

  1. Njuguna J and Pielichowski K 2004 Polymer nanocomposites for aerospace applications: fabrication. Adv. Eng. Mater. 6(4): 193–203

    Article  Google Scholar 

  2. Njuguna J, Pielichowski K and Alcock J R 2007 Epoxy-based fiber reinforced nanocomposites. Adv. Eng. Mater. 9(10): 835–847

    Article  Google Scholar 

  3. Godara A, Mezzo L, Luizi F, Warrier A, Lomov S V, Van Vuure A W, Gorbatikh L, Moldenaers P and Verpoest I 2009 Influence of carbon nanotube reinforcement on the processing and the mechanical behaviour of carbon fiber/epoxy composites. Carbon 47(12): 2914–2923

    Article  Google Scholar 

  4. Sahoo N G, Rana S, Cho J W, Li L and Chan S H 2010 Polymer nanocomposites based on functionalized carbon nanotubes. Prog. Polym. Sci. 35(7): 837–867

    Article  Google Scholar 

  5. Xie X L, Mai Y W and Zhou X P 2005 Dispersion and alignment of carbon nanotubes in polymer matrix: a review. Mater. Sci. Eng. R 49(4): 89–112

    Article  Google Scholar 

  6. Yaping Z, Aibo Z, Quinghua C, Jiaoxia Z and Rongchang N 2006 Functionalized effect on carbon nanotube/epoxy nano-composites. Mater. Sci. Eng. A 435–436: 145–149

    Article  Google Scholar 

  7. Ma P C, Mo S Y, Tang B Z and Kim J K 2010 Dispersion, interfacial interaction and re-agglomeration of functionalized carbon nanotubes in epoxy composites. Carbon 48(6): 1824–1834

    Article  Google Scholar 

  8. Gojny F H, Wichmann M H G, Fiedler B and Schulte K 2005 Influence of different carbon nanotubes on the mechanical properties of epoxy matrix composites – a comparative study. Compos. Sci. Technol. 65(15–16): 2300–2313

    Article  Google Scholar 

  9. Shen J, Huang W, Wu L, Hu Y and Ye M 2007 The reinforcement role of different amino-functionalized multi-walled carbon nanotubes in epoxy nanocomposites. Compos. Sci. Technol. 67(15–16): 3041–3050

    Article  Google Scholar 

  10. Thostenson E T and Chou T W 2006 Processing-structure-multi-functional property relationship in carbon nanotube/epoxy composites. Carbon 44(14): 3022–3029

    Article  Google Scholar 

  11. Zhou Y, Pervin F, Lewis L and Jeelani S 2008 Fabrication and characterization of carbon/epoxy composites mixed with multi-walled carbon nanotubes. Mater. Sci. Eng. A 475(1–2): 157–165

    Article  Google Scholar 

  12. Sun L, Warren G L, Reilly J Y O, Everett W N, Lee S M and Davis D 2008 Mechanical properties of surface-functionalized SWCNT/epoxy composites. Carbon 46(2): 320–328

    Article  Google Scholar 

  13. Ma P C, Kim J K and Tang B Z 2007 Effects of silane functionalization on the properties of carbon nanotube/epoxy nanocomposites. Compos. Sci. Technol. 67(14): 2965–2972

    Article  Google Scholar 

  14. Yokozeki T, Iwahori Y, Ishibashi M, Yanagisawa T, Imai K and Arai M 2009 Fracture toughness improvement of CFRP laminates by dispersion of cupstacked carbon nanotubes. Compos. Sci. Technol. 69(14): 2268–2273

    Article  Google Scholar 

  15. Gan Y 2009 Effect of interface structure on mechanical properties of advanced composite materials. Int. J. Mol. Sci. 10: 5115–5134

    Article  Google Scholar 

  16. Lee J S and Kang T J 1997 Changes in physico-chemical and morphological properties of carbon fiber by surface treatment. Carbon 35: 209

    Article  Google Scholar 

  17. Zhang F H, Wang R G, He X D, Wang C and Ren L N 2009 Interfacial shearing strength and reinforcing mechanisms of an epoxy composite reinforced using a carbon nanotube/carbon fiber hybrid. J. Mater. Sci. 44: 3574–3577

    Article  Google Scholar 

  18. Baughman R H, Zakhidov A A and De Heer W A 2002 Carbon nanotubes – the route toward applications. Science 297: 787–792

    Article  Google Scholar 

  19. Montazeri A, Javadpour J, Khavandi A, Tcharkhtchi A and Mohajeri A 2010 Mechanical properties of multi-walled carbon nanotube/epoxy composites. Mater. Des. 31: 4202–4208

    Article  Google Scholar 

  20. Hung K H, Kuo W S, Ko T H, Tzeng S S and Yan CF 2009 Processing and tensile characterization of composites composed of carbon nanotube grown carbon fibers. Composites: Part A 40: 1299–1304

    Article  Google Scholar 

  21. Bal S and Samal S S 2007 Carbon nanotube reinforced polymer composites – a state of the art. Bull. Mater. Sci. 30(4): 379–386

    Article  Google Scholar 

  22. Evans A G 1990 Perspective on the development of high toughness ceramics. J. Am. Ceram. Soc. 73: 187–206

    Article  Google Scholar 

  23. Lubineau G and Rahaman A 2012 A review of strategies for improving the degradation properties of laminated continuous fiber/epoxy composites with carbon based nano reinforcements. Carbon 50: 2377–2395

    Article  Google Scholar 

  24. Nair S V and Wang Y L 1990 Toughening behaviour of a two dimensional SiC/SiC woven composite at ambient temperature: I. Damage initiation and R-curve behavior; II. Stress displacement relationship in the crack process zone. J. Am. Ceram. Soc. 81: 1149 & 1157

  25. Ayatollahi M R, Shadlou S and Shokrieh M M 2011 Fracture toughness of epoxy/multi-walled carbon nanotube nano-composites under bending and shear loading conditions. Mater. Des. 32(4): 2115–2124

    Article  Google Scholar 

  26. Hernández-Pérez A, Avilés F, May-Pat A, Valadez-González A, Herrera-Franco P J and Bartolo-Pérez P 2008 Effective properties of multiwalled carbon nanotube/epoxy composites using two different tubes. Compos. Sci. Technol. 68(6): 1422–1431

    Article  Google Scholar 

  27. Chandra Shekar K, Sai Priya M, Subramanian P K, Anil Kumar, Anjaneya Prasad B and Eswara Prasad N 2014a Processing, structure and flexural strength properties CNT and carbon fiber reinforced epoxy matrix hybrid composite. Bull. Mater. Sci. 37(3): 597–602

    Article  Google Scholar 

  28. Chandra Shekar K, Anjaneya Prasad B and Eswara Prasad N 2014b Effect of amino multi-walled carbon nanotubes reinforcement on the flexural properties of neat epoxy. Appl. Mech. Mater. 592–594: 912–916

    Article  Google Scholar 

  29. Chandra Shekar K, Anjaneya Prasad B and Eswara Prasad N 2014c Interlaminar shear strength of multi-walled carbon nanotube and carbon fiber reinforced, epoxy-matrix hybrid composite. Proc. Mater. Sci. 6: 1336–1343

    Article  Google Scholar 

  30. Damani R, Gstrein R and Danzer R 1996 Critical notch root radius in SENB-S fracture toughness testing. J. Eur. Ceram. Soc. 16(7): 695–702

    Article  Google Scholar 

  31. Eugênio de Azevedo Soriano and Sérgio Frascino Müller de Almeida 1999 Notch sensitivity of carbon/epoxy fabric laminates. Compos. Sci. Technol. 59(8): 1143–1151

  32. Lagace P A 1986 Notch sensitivity of graphite/epoxy fabric laminates. Compos. Sci. Technol. 26(2): 95–117

    Article  Google Scholar 

  33. Özcoban H, Jelitto H and Schneider G A 2010 Influence of finite notch root radius and optically determined crack length on the measured fracture toughness of brittle materials. J. Eur. Ceram. Soc. 30(7): 1579–1583

    Article  Google Scholar 

  34. Picard D, Leguillon D and Putot C 2006 A method to estimate the influence of the notch-root radius on the fracture toughness measurement of ceramics. J. Eur. Ceram. 26(8): 1421–1427

    Article  Google Scholar 

  35. Chandra Shekar K, Anjaneya Prasad B and Eswara Prasad N 2015a Effect of notch root radius on the fracture toughness of epoxy and 0.5 wt.% amino MWCNTs-reinforced nanocomposite. Trans. Ind. Inst. Met. DOI:10.1007/s12666-015-0623-8

  36. Chandra Shekar K, Naveen Kumar M, Subramanian P K, Anil Kumar, Anjaneya Prasad B and Eswara Prasad N 2014d Effect of notch root radius on the apparent fracture toughness in CNT and carbon fiber reinforced, epoxy-matrix hybrid composite. Trans. Ind. Inst. Met. 67(1): 33–39

    Article  Google Scholar 

  37. Crowe C R and Gray R A 1984 Failure mechanisms in high performance composites. In: Proceedings of the 39th meeting of High Performance Group, pp. 157–166

  38. Chandra Shekar K, Anjaneya Prasad B and Eswara Prasad N 2015b Effect of amino multi-walled carbon nanotubes reinforcement on the plane strain fracture toughness of neat epoxy. J. Aerosp. Sci. Technol. 67(2B): 330–334

    Google Scholar 

  39. Landes J D and Begley J A 1972 Test results from J-integral studies: an attempt to establish a JIc test procedure. In: Fracture analysis. ASTM 170–186

  40. Begley J A and Landes L D 1972 The J-integral as a fracture criterion: the effect of specimen geometry on JIc. In: Fracture toughness. ASTM 24

  41. Rice J R 1968 A path independent integral and the approximate analysis of the strain concentration by cracks and notches. J. Appl. Mech. Trans. ASME 35: 379–386

    Article  Google Scholar 

  42. Hashida T, Li V C and Takahashi H 1994 Development of the J-based fracture testing technique for ceramic-matrix composites. J. Am. Ceram. Soc. 77(6): 1553–1561

    Article  Google Scholar 

  43. Nair S V and Wang Y L 1998 R-curve behavior of silicon ceramic reinforced with silicon carbide platelets. J. Am. Ceram. Soc. 81(8): 1149–1156

    Google Scholar 

  44. Chandra Shekar K, Krishna Kanth N, Subramanian P K, Anil Kumar, Anjaneya Prasad B and Eswara Prasad N 2015c Fracture behaviour of carbon nanotube and carbon fiber-reinforced, epoxy-matrix hybrid composite. Int. J. Mater. Product Technol. 51(1): 1–16

    Article  Google Scholar 

  45. Eswara Prasad N, Sweety Kumari, Kamat S V, Vijayakumar M and Malakondaiah G 2004 Fracture behaviour of 2D-weaved, silica–silica continuous fiber-reinforced, ceramic–matrix composites (CFCCs). Eng. Fract. Mech. 71(18): 2589–2605

    Article  Google Scholar 

  46. Chen J H, Schulz E, Bohse J and Hinrichsen G 1999 Effect of fiber content on the interlaminar fracture toughness of unidirectional glass-fiber/polyamide composite. Composites Part A 30(6): 747–755

    Article  Google Scholar 

  47. Lachman N and Daniel Wagner H 2010 Correlation between interfacial molecular structure and mechanics in CNT/epoxy nano-composites. Composite Part A 41(9): 1093–1098

    Article  Google Scholar 

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Acknowledgement

The authors are grateful to Sri Anil Kumar, Group Head, HTCC, ASL, and Dr I. Srikanth, Scientist of ASL, DRDO, for many fruitful discussions and also for the help rendered during material processing and experimental work. Authors also thank SAIF, IIT Bombay, for FEG-SEM analysis of the composites.

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CHANDRA SHEKAR, K., ANJANEYA PRASAD, B. & ESWARA PRASAD, N. Strengthening in and fracture behaviour of CNT and carbon-fibre-reinforced epoxy–matrix hybrid composite. Sādhanā 41, 1443–1461 (2016). https://doi.org/10.1007/s12046-016-0566-8

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  • DOI: https://doi.org/10.1007/s12046-016-0566-8

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